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Novel Low Temperature UV-assisted Rapid Thermal Annealing of Ferroelectric Materials
The crystallization of the ferroelectric perovskite phase of modified lead titanate (mPT) from sol-gel layer has been achieved at a temperature as low as 550°C using ultraviolet-assisted rapid thermal processing (UV-RTP). This compares well to the temperature of 650°C required to develop the same perovskite phase of mPT using purely thermal RTP.

The reduction in the maximum processing temperature achieved by UV-RTP opens the possibility for wider applications of ferroelectrics, high-k and oxide materials on thermally sensitive substrates and structures (above IC for instance).

UV is used for bond cleavage, while the thermal process at 550° C is used for development of the perovskite crystal phase.
Samples prepared by this process proved to be single phase.
Dielectric constant =166
Loss tangent = 0.08
Maximum pyroelectric coefficient = 16 x 10-9 C.cm-2.K-1 Remanent polarization, Pr = 22 mC.cm-2
Longitudinal coefficient, d33 = 38pm/V
UV-RTP processes were performed in the Jipelec JetClip sg reactor (patented technology) with both IR halogen lamps (for RTP capabilities) and high power UV excimer lamps.
Jipelec offers customer demonstrations and tests upon request
For further information please contact:
Dr. H. GUILLON
JIPELEC

11, Chemin du Vieux Chêne
38240 MEYLAN ZIRST
FRANCE
Phone: 33 476 04 06 06
Fax: 33 476 04 81 40
guillon@jipelec.com
Dr. P.V. KELLY
NMRC
Lee Maltings
Prospect Row
Cork
IRELAND
pkelly@nmrc.ie
Dr L. PARDO
ICMM-CSIC

Cantoblanco
E-28049 MADRID
SPAIN
lpardo@icmm.csic.es
Dr. I. STOLITCHNOV
EPFL

Ceramics Laboratory
Swiss Fed. Inst. of Tech.
CH-1015 Lausanne
SWITZERLAND
igor.stolitchnov@epfl.ch
This work was partly funded by the European Commission under Brite-Euram project BRPR-CT98-0777 (MUVAST)

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